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Programming with .net

I've just recently learned C# and am interested in .net but I don't know where to begin.
I know .net is just a bunch of libraries and can be used for web programming?
I'm not quite sure what areas in .net that I need to learn?
I don't know what I am trying to accomplish with .net? But I want to learn .net.
What other things can be achieved with .net?
Thanks.
Added -
The 2D class that I finished was a C#/Winform/XNA class working with 2d objects. Though there was never once a reference about .net in class. I just learned C# which is comparable to C++ and Java and Winform = just using the tool box and hooking up controls to back end code. XNA portion was being able to use the hardware to draw primitives and manipulate data going through the model->view->project pipeline.
What part of this class was .net? None right?

You can do nearly anything with .net (the same is true for most other platforms).
You can use ASP.NET for web programming, Windows Forms or Windows Presentation Foundation for GUI development.
There are also lots of functionality for networking, database development and XML or Image processing.
But the question is, what do you want to achieve?

I know .net is just a bunch of libraries and can be used for web programming?
.NET is much more than this. It is not restricted to web programming. There are possibilities for doing Windows Applications (WPF), Web Applications (ASP.NET), Network Communication (WCF), Database Access (ADO.NET), ..., you name it. So just pick a language you would like to learn like C# and go ahead and visit MSDN.

.Net is a managed runtime with libraries. It is not exclusive to building "web" applciation or pages.
The .Net Framework is 'the libraries'.
The CLR is the runtime (where the specification thereof, is deposited into a standarization organization)
C#/VB.Net/F# are flavors of different syntaxus (how do you spell this in plural?) used to instruct the runtime, using the libraries, to perform actions in an order you define (AKA programming)
Wanting to learn .Net is akin to learning another language/gammar. If you have no previous knowledge of "language/gammar" itself, you are using this specific language/runtime to learn 'language' in general.
Hope this helps,

Sorry, but if you've just used the toolbox to hook some stuff together you haven't learned C# or programming. You've learned how to hook some stuff together, but you're obviously interested in learning how it works. Seems like you're going to have to learn a lot of stuff from scratch. There's a lot to learn...
I think your best bet to learn .Net and C# (you can't really learn one without the other) apart from following a course specific for that goal is to find yourself a good book that explains the whole picture and run through the examples in the book.
Looking on internet, asking questions, and collecting bits of examples, etc. will give you little pieces of understanding, but I doubt you'll be able to get a comprehensive understanding of programming, .Net and C# that way, simply because you won't find a big picture explanation. I find a good book gives me a deeper understanding even though I've already worked with .Net/C# since it first came out, simply because there is much more explanation of how things work and why.
Personally I really like the Pro series from Apress: have a look at Pro C# 2010 and the .Net 4 Platform
It might be perfect or not depending on your understanding of software development. Otherwise just search for C# and see if other interesting books pop up.

Is there a reason I should not start with C#

I think I'm leaning toward C# and .net as a concentration language for learning web development. I would like to learn good programming fundamentals and I've looked at pretty much everything else. The four I've narrowed it down to have been C#, Python, Ruby and PHP. Is there a reason to stay away from C# (and I don't think the cost issue would really apply to my solo-developer situation but I could be totally wrong). Any thoughts?
I realize that these are all great languages so I'm not trying to ask which is the best overall. However, would Ruby be a viable alternative for a first language or does it have too much "magic under the hood" coupled with Rails, and unorthodox methodologies? I do like what I've seen with the language.

This is likely to result in a flamewar but I think C# is a pretty good language to start with for Web Development.
It is a full featured object oriented language and is statically typed and compiled. It's very well documented and has a huge developer community.
If you absolutely have to run on Linux/Apache and do not want to use Mono, that would be a reason not to use C#. Other than that, I don't think there is a compelling reason not to, particularly with ASP.NET MVC, which lets you move away from the WebForms model.
This is not to say that WebForms is necessarily bad but some might object to WebForms as it introduces abstractions that are not inherent in other web development platforms.

If you go with C# for web development, depending on your experience with web technology, I'd heartily recommend starting with ASP.NET MVC before ASP.NET Web Forms.
ASP.NET Web Forms is the original style of building ASP.NET applications, and tries to abstract a lot of the details. It allows you to build applications without realising what's happening under the hood (post data, state management). In my opinion, these abstractions although making things easy at first begin to "leak" when you get into more complicated scenarios (as this tutorial proves).
ASP.NET MVC on the other hand makes it easier to build web sites that are a lot "closer to the metal" while still keeping you productive. If you want absolute control over the resulting HTML and aren't afraid of things like cookies, form tags, post and query string data, then you might enjoy ASP.NET MVC a lot more.
Of course it would be beneficial to know both. But if I was starting now, I'd probably start with MVC and move to Forms (then realise how bad it is and move back :)).

There are no "best language over all". You use one tool for the purpose it has been made, that's why there are several tools.
Since your question is "why not learn C#", I'd say :
If you plan to work with other OS then Windows (Mono cannot compare).
If work in an env or with people not .net friendly (e.g : bank, scientists)
If you work in an env or with people that are expert in another good tech (never underestimate the use of a good master).
If you think Free Software matters so much that using a MS product is not worth it.
If you don't like MS Visual Studio (working in c# without a good IDE is a pain).
If You plan to program something that .net is not suited for (e.g embedded devices, scripting, real-time, fault tolerant system, AI, etc).
If you are a web dev and can't afford a Windows Server Licence.
If you want to learn programming with the very basics, including simple functions and quick and dirty scripts.
Now, I program in Php, Python, Java and C#. Python is my language of choice, but c# is really the first MS programming tool that seduced me : it's clean and efficient. Really, it's about what you want to do, not a question of religion.
Make YOUR choice.
That's said, C# sucks and Python rocks.

I agree C# is a pretty complete language, it's syntax is clean and extensible. There's a huge amount of web resource already available, but and it's a big but, it effectively ties you to windows as your platform. For web especially that's an important consideration. On the desktop windows is king, but for web servers the market it isn't nearly so dominant.
Another side issue, if you're looking at rich media on the web you have to consider Flash and/or Silverlight. If you go C# then you're someway to using Silverlight without learning a different language.

Don't worry about the cost. The compiler is free to use, along with the rest of the Fx SDK, and you can even download Visual Studio for free.

The disadvantage to learning C# is that it ties you to a proprietary platform and software stack. Now, there is Mono, which does a good job of implementing much of C# and .Net, but the primary and most complete implementation is Microsoft's which is non-free.
I have not used C# enough to debate it's technical merits with respect to Ruby or Python. I can say, however, that learning to use and even contribute back to free software can be quite educational, in addition to the other benefits (discussed in length elsewhere) that free software provides.

c# is a good language to start with because:
It is a very good and very clean language
It has an excellent library (.NET framework). This is one of the most important things to consider when choosing a language.
It is very popular, you'll always be able to find the answer you are looking for from the community.
If you know c#, you pretty much know VB.NET.
c# is syntactically similar to Java. Learning c# won't teach you Java's libraries, but it will significantly reduce the learning curve if you want to enter the Java camp.
c# is syntactically similar to c++. Again, it uses a different library and unlike c++ you get memory management; but the learning curve should be somewhat reduced if you decide to play with c++.
As for the web...
ASP.NET webforms does a lot of magic for you. ASP.NET MVC (just released) does almost no magic for you. For learning, MVC is the better choice.

C# is a great language to use. And since you are using it via the web and not desktop applications for example, you don't have to worry about being multi-platform since the code is run on your server and the output delivered to the clients. With that said, you will have to find Windows hosting (which can sometimes be a bit more expensive) or use mono (which isn't exactly the most updated software out there). The downsides are minimal though, grab a copy of the express edition and go for it!

I think the cost of deployment might be a different thing, i.e. if your project needs to scale horizontally, and add more servers to load balance or even for geographically distributed servers. Usually the windows hosting will run a bit more than linux (without even considering the flame wars reasons).

C# is fine for starting if you are doing web development. However, I recommend that you don't start programming with web development. Web development is hard to get right. Way harder than little command line things. I recommend that you get some good experience programming for the command line, and then move up to GUI, and then move on to the web. The web has a whole bunch of things you have to worry about. You have to know 3 languages (HTML, JS, C#(or insert your server side language here)). Plus you have to worry about all the browser quirks and stuff. And that's without even getting into databases. Which is usually used in most web applications, but opens up a whole other can of worms.

Considering all the answers so far, I thought I'd look at all four languages mentioned.
While I've done a lot of development in PHP, and sadly continue to do so, I think PHP was never a great language (though it had a few great elements) and these days there's not much point picking it up. It remains extremely easy to get into but I think in general, PHP is a "bad habit".
Python is a great language, but to me, Ruby is all that Python is and a bit more. Personally I would go for Ruby.
C# is also a great language, but while I haven't used C# enough to say anything with confidence, I feel that Ruby is a better choice.

No reason in particular to stay away from C#. It's as good a language as any. Stackoverflow uses it for example, so it works on a successful website, and you can get jobs programming in it.
The proprietary thing would be a consideration if you were programming as a hobby or off your own limited budget, or you wanted to contribute to the development of the compiler/language. I'm guessing neither of these are the case. (Edit: as others have pointed out, open source environments for C# exist.)

It depends on a couple of things. C# and .Net is populate and th tools are really very easy (complared to Java! Java developer talking here...) but Windows Hosting is expensive vs LAMP (which include Ruby, Python and PHP).
For me it all depends on the tool that you want to use. For web services etc I would use C# but for a simple website PHP since its easy.
It also depends on the job market of your location... here in South Africa you get alot more C# jobs and not much PHP etc. Off course if your a freelance you will struggle to find work.
For me Ruby again is good for my own person stuff but you don't get any Ruby jobs here.

My advice? Learn the differences for yourself. Play around with both of them. If you have a project in mind, write a prototype for it in them. You'll always be at the mercy of other peoples' biases otherwise.
ASP.net (C#) and Ruby on Rails are used in high-profile sites, so you can't go too wrong with either one. Might I also suggest that you try out Python programming with django? It's what I tend to prefer for web programming.

I'm a C# .Net developer and I think it's great, but I'll highlight a danger in the Asp.Net WebForms. It is unlike the majority of other web frameworks and does A LOT of magic under the covers. As others have said ASP.Net MVC is probably more inline with other web frameworks (Rails for example). Web Forms abstracts a lot of the nuts and bolts of webdev away which If you want to be web developer you'll end up needing to know. So yes C# is great but I'd start with MVC and then look at web forms possibly. Also looking at other languages and frameworks is highly encouraged there's always stuff to learn.

Commercially I am a C# developer. I love C#. C# is a great strongly typed language. With Resharper installed I can build my ideas in code rapidly and flex it to my will.
When I go home each evening I use Ruby. Even though I have no refactoring support (snif.) I find I am much more productive in Ruby than in C#.
I worked writing a large ASP.Net application for a couple of years. We implemented MVC to try to detangle the view from the model. It always felt like I was fighting the framework, not working with it. The latest .Net frameworks for doing web application are based on Rails... just a couple of years behind. I love the language. I love the CLR. I'm not too keen on .Net.
I find the ruby community to be friendly and vibrant. The rails open source community produces loads of tutorials and plugins that make getting up to speed easy and putting your application together simple.
Another thing to consider (as far as choosing a language to learn) is that ruby is an Object Oriented language. Even classes are objects. C# is a Class Oriented language, ie. it provides you one way to create objects.. define a class first. (not totally true.. you can generate assemblies in memory using codedom.. but that is by no means easy).
This may seem like a subtle point, but there is a difference.. and until you get experience with an OO language like ruby or smalltalk it's not obvious what that is. Once you have felt the freedom of building objects by mixing in functionality at runtime etc. you find that all the 'work-around's you had to do in C# disappear. Not having the safety net of interfaces does seems scary at first.
In all, I'd learn ruby..
If you are new to programming (totally) I'd start with http://pine.fm/LearnToProgram/
Then I would learn BDD (RSpec) and get test infected as soon as possible.
Then I'd consume rails tutorials and screen casts until my eyes popped
The only problem is .. if you start with ruby then later go to C# you'll find yourself going "Aaaaagh! This would be so much easier to do in ruby" all the time. I know I do.

It really depends on what you are trying to achieve. I program in both and to be brutally honest, if you are trying to make a career out of programming, I get paid twice as much for .NET programming. The types of clients that I do PHP dev work for are not the types that pay a lot (PHP is often chosen based on saving some $$$). .NET seems to be much more entrenched in larger corporations.
Just my observation...

No disadvantages really except that you will be unwelcome in those social groups (and even geographical regions) that pose themselves against the "evil Microsoft".
The language (better .NET platform) is quite good. One important thing is that it is being very actively developed causing some people trouble keeping up. But I'd rather have rapid development compared to year-long stagnation.
You might consider checking what employers in your area prefer as a technology stack.
Considering licensing costs you can consider the following: If it is a small site you can use Visual Studio Express/SQL Server Express for free and it will be sufficient. If you come up with some major heavy trafficked project you will likely to find a way to make revenues and cover licensing costs.

Learning C# is great in 2009.
Way back in the day, when I entered the professional world, the language landscape was very different. I coded professionally in C and Modula 3 (Pascal replacement language).
My point is that I would plan for the technical landscape to change over time, and plan for that in your professional career development.
Learning multiple platforms is a great way to accomplish this. For example, you could have C#/.NET as your primary skill, but also work with JAVA. When a new platform emerges, you could add it as your transition or backup skillset.

Looking for feedback from people that have gone from 100% web development to winforms

I have been a web developer for my entire development career. Nearly 100% microsoft focused the entire time. I have been using .Net, both C# and VB.Net, since beta. I now find myself in a position to where I have the opportunity to start doing some WinForms development in C# using the 3.5 framework. As with anything new, I am excited about the learning opportunity in front of me.
I am curious if anyone has any suggested books, articles, feedback, etc on the topic of transitioning from web development to winforms in the .Net world.

I think it goes without saying that the paradigms are very different. I really enjoy C# because of how easy it is to write great windows software.
Start by getting into the IDE and creating a real but small project. One of my first C# projects was a light weight budget program. That took me into many areas of C#, from XML handling to custom windows controls, to debugging, and more.
Experience is the best teacher. Take time to look at the function lists, and peruse the documentation. Get a feel for what is in the thousands of classes that make up .NET.
Reading books can be nice, but getting your hands dirty (in conjunction with a good book) is far more effective.
Set a goal and go for it, you will have no problem learning all about it. Don't be afraid to try things and take risks -- it helps you learn the system.

If you are moving from Web to Windows, there is a some significant differences between the two enviroments. Some good and some are bad. If your .Net based and moving to 3.5 look into WPF since it is the best of both worlds for Web developers converting right now.
I do know of some common mistakes made by web developers making the crossover. They would include:
Opening database connections on every form and every database calls. (In Windows Bad)
There is no ViewState concept or Stateless concept in Windows
I am sure there is a few more that can be added but right now I can't think of an exact list.
I do agree with gahooa, look at doing a small project and read as much as possible on the subject. Approach it as if you never developed before, and the skills you gained over the years will automatically kick in when needed.

How to stop worrying about using the best materials and just start learning .Net?

For the past few years whenever I learn something I tend to spend way too much time researching on the best materials for the subject than actually studying it. What should I do to get over this mentality? I am stuck. How to stop worrying about getting or using the BEST books, training videos and online materials on .net and just start learning?

Start doing a project with a deadline. You will code and learn together. If you cannot do that at work, think of a hobby project with some real requirements (like building a photo sharing site).

I completely agree on the just start coding philosophy. Another idea for a project is to go through the Project Euler exercises. They are somewhat simple math problems that get progressively harder. It is great if you can not think of a project or only have a little bit of time. Then just use a reference book, or the internet to learn what you need to about the language specifics.

Go download Visual Studio Express
http://www.microsoft.com/Express/
Go buy one of the following books:
ASP.NET 3.5 Step by Step
C# 2008 Step by Step
VB.NET 2008 Step by Step
From my experience (when I first started with .NET back in the 1.0 days) the Step by Step books from Microsoft are the best at just starting out and getting your feet wet with .NET.

1) Stop researching
2) Start programming
Seriously, the only book you need to program in .NET is CLR Via C# by Jeffrey Richter. Read it cover to cover (save the first couple chapters until you've read the rest, btw), and start coding. When you hit stuff you have problems with (Linq, WPF, source control, unit testing), come here.

Buy visual studio 08, devise a small project, and complete it.
Make a deadline for yourself and don't push it back.
Buy a basic C# book for reference, don't worry about which one.
You can do it!

Firstly, don't beat yourself up for not having done things the right way before, as I'm sure you know, there never is a right way. Also, some of that searching for the best resources will pay for itself when you have a better understanding of things than the next guy. And, as has already been said, do a project, pick something harder than the usual, trivial examples, so that you have to think and ask questions and do some research. Finally, if you have a blog then post about what you are up to, that way you'll have more of a sense of a commitment to stay working on the project rather than bailing out as it gets hard, especially as that is usually the time when you are about to actually learn something (this works for me anyway!)

There is no single best resource on anything. The best way to learn is to practice. Get any book to get yourself started. Then just start writing some code at home. Play with the language and the platform. Read blogs, browse the questions here. You will start discovering and learning nuggets of information.
Others mentioned buying Visual Studio 2008. It can be an expensive investment although it is totally worth it if you are a independent developer/consultant. However, if you just need something to get you started with coding, get the free Visual C# Express. You can always grow into the professional SKUs when you need it.

The best way is learn by doing!

When you work at a new job, you learn a lot because you have great individuals who transfer a lot of knowledge they find useful. You can review how they do things, which parts are done well and which parts are done poorly.
Learning by isolation is hard especially when there are so many resources out there.
I recommend connecting with individuals in your local community user group or an online group, or start your own group. Many of these individuals will have had real-world experience and can help direct your learning path more effectively.

Find an area of .Net you'd like to use, e.g. console Applications, Windows Applications, ASP.Net applications, web services, and just build a few little "getting your feet wet" sort of things like the basic "Hello World!" example or doing some simple computations or using an MS-SQL back-end if you do get SQL Express or the richer versions.
Don't forget that if you don't get in, some things may pass you by. How many ASP.Net 1.0 or 1.1 apps are out there using older systems that you may not be familiar with yet may be an incentive to start doing rather than trying to find the BEST that will be out of date in a few years. Take some of the ideas from a book like "Refactoring" by Martin Fowler if you want to program something a little bigger than the simple "Hello World!" program.

Download Visual C# Express 2008. Google for intro tutorials. Dig in and explore yourself.
This URL is all you need to get started with .NET:
http://msdn.microsoft.com/en-us/vcsharp/aa336768.aspx?wt.slv=RightRail
If you want mastery of .NET, there a lot of different ideas, but only one official self-education track. Get the official MCTS / MCPD training guides from Microsoft Press. These are searchable on Amazon by Exam number, such as Exam 70-536. But as long as you know how to Google for questions and tutorials, you don't need much else.

ASP.NET MVC Contrib Projects

I am looking to get on with contributors on an ASP.NET MVC Project. I am professionally developing for a large firm and don't get enough of it here. I also teach Java Object Oriented practices at a University, and still don't feel that I get enough of the engineering with this. Simply put, I am looking to get onto a project (small, opensource) so that I can gain valuable information and learn from others in the community before I go crazy here (I have reached a proverbial ceiling where I am).
Where is the best place to look for this type of work?
My wannabe expertises... JQuery, ASP.NET MVC, CSharp, AJAX, Javascript, Memberships, and the list continues on. Previous work is mostly private (intranet), so all I have is a couple sites I have put together. http://jancel.doesntexist.com (is one that I am currently working on, won't be here forever, just waiting for customer buyoff). http://hurl.me is the first MVC C# Project I took on to learn more on ASP.NET MVC C#. My experiences started at Preview 2 and am excited to get on board here.

There are any number of open source projects that could easily use a major refactoring of their codebase (and know it). I'd start with SourceForge, find a few you're interested in for their subject matter, and start a conversation. (From your point of view, they don't even need to be currently ASP sites.)

How about MvcContrib? Another thought is Code Camp Server, but I'm not sure how active it is in terms of new features.